Prep: Preheat oven to 350°F (175°C). Grease a loaf pan and line with parchment paper.
Flavor Sugar: In a large bowl, rub the orange zest into the sugar with your fingers until fragrant.
Wet Ingredients: Whisk the melted butter into the sugar. Add eggs one at a time. Stir in yogurt, orange juice, and vanilla.
Dry Ingredients: In a small bowl, whisk flour, cocoa, baking powder, baking soda, and salt.
Combine: Add dry mix to wet mix. Fold gently with a spatula until just combined.
Add Chocolate: Fold in ¾ cup of the chocolate chunks.
Bake: Pour batter into the pan. Top with remaining chocolate. Bake for 50–60 minutes.
Cool: Cool in pan for 15 minutes, then transfer to a wire rack.